4-[Bis(4-fluorophenyl)methyl]piperazin-1-ium bis(trichloroacetate) 0.4-hydrate

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4-[Bis(4-fluoro­phen­yl)meth­yl]piperazin-1-ium bis­(trichloro­acetate) 0.4-hydrate

The title compound, C(17)H(20)F(2)N(2) (2+)·2C(2)Cl(3)O(2) (-)·0.4H(2)O, has twofold protonated N atoms. The trichloro-acetate anions each show one disordered Cl atom with site occupation factors of 0.945 (7):0.055 (7) 0.945 (8):0.055 (8). In the crystal, N-H⋯O, O(water)-H⋯O and O(water)-H⋯F inter-actions connect the components into a three-dimensional network.

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2′,6′-Bis(4-carb­oxy­phen­yl)-4,4′-bipyridin-1-ium nitrate 0.25-hydrate

In the title compound, C(24)H(17)N(2)O(4) (+)·NO(3) (-)·0.25H(2)O, the central pyridine ring of the 2',6'-bis-(4-carb-oxy-phen-yl)-4,4'-bipyridin-1-ium cation is almost coplanar with one benzene ring [dihedral angle = 1.03 (5)°], while it makes dihedral angles of 9.59 (5)° with the other benzene ring and 13.66 (6)° with the pyridinium ring. In the crystal, N-H⋯O and O-H⋯O hydrogen bonds link th...

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4-(4-Methoxy­phen­yl)piperazin-1-ium chloride

In the title compound, C(11)H(17)N(2)O(+)·Cl(-), the dihedral angle between the benzene ring and the basal plane of piperazine ring is 39.20 (8)°. In the crystal, intermolecular N-H⋯Cl hydrogen bonds occur. There is also a C-H⋯π inter-action between the benzene rings.

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4-Carboxy­pyridazin-1-ium chloride

The structure of the title compound, C(5)H(5)N(2)O(2) (+)·Cl(-), is composed of chloride anions and 4-carboxy-pyridazin-1-ium cations. Chloride anions bridge the cations via O-H⋯Cl and N-H⋯Cl hydrogen bonds to form ribbons. The latter, linked by van der Waals forces with lengths in the range 3.254 (2)-3.497 (2) Å, form coplanar layers. Very weak inter-actions operate also between adjacent layer...

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4-Thio­carbamoylpyridin-1-ium iodide

The title salt, C6H7N2S(+)·I(-), crystallizes with two independent cations and two anions in the asymmetric unit. In one of the cations, the dihedral angle between the pyridinium ring and the thioamide group is 28.9 (2)°; in the other it is 33.5 (2)°. In the crystal, N-H⋯S and C-H⋯S hydrogen bonds link the independent cations into pairs. These pairs form a three-dimensional network through addi...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812009282